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HH一sulfide-III硫?qū)S弥?測(cè)定煤基合成氣中硫化氫及羰基硫

HH一sulfide-III硫?qū)S弥?測(cè)定煤基合成氣中硫化氫及羰基硫

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產(chǎn)品名稱:HH一sulfide-III硫?qū)S弥?測(cè)定煤基合成氣中硫化氫及羰基硫

產(chǎn)品型號(hào):HH一sulfide-III硫?qū)S弥?/p>

產(chǎn)品廠商:浩瀚色譜(山東)應(yīng)用技術(shù)開(kāi)發(fā)有限公司

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測(cè)定煤基合成氣中硫化氫及羰基硫,芝麻香白酒,3-甲硫基丙醇,室內(nèi)空氣,焦?fàn)t煤氣,煉廠氣,變壓器油,多氯聯(lián)苯,植物油,增塑劑,塑化劑,室內(nèi)空氣TVOC,頂空進(jìn)樣器,環(huán)氧乙烷EO

HH一sulfide-III硫?qū)S弥?測(cè)定煤基合成氣中硫化氫及羰基硫的詳細(xì)介紹

測(cè)定煤基合成氣中硫化氫及羰基硫
測(cè)定煤基合成氣中硫化氫及羰基硫  詳細(xì)信息:

名稱:硫化物測(cè)定專用柱

材質(zhì):聚四氟乙烯管

型號(hào):HH一sulfide-III

規(guī)格:3m*3mm

使用溫度:120°C

浩瀚色譜(山東)應(yīng)用技術(shù)開(kāi)發(fā)有限公司建立了測(cè)定煤基合成氣中H_2S及羰基硫含量的氣相色譜分析方法,采用火焰光度檢測(cè)器(FPD)檢測(cè),進(jìn)樣系統(tǒng)硫鈍化處理,標(biāo)氣由在線稀釋系統(tǒng)稀釋成5個(gè)濃度,相對(duì)保留時(shí)間定性,工作曲線外標(biāo)法定量。H_2S含量的對(duì)數(shù)與峰面積對(duì)數(shù)在0.07~0.30 mg/m3范圍內(nèi)線性關(guān)系良好,相關(guān)系數(shù)r2為0.9998;羰基硫含量的對(duì)數(shù)與峰面積對(duì)數(shù)在0.13~0.53 mg/m~3范圍內(nèi)線性關(guān)系良好,相關(guān)系數(shù)r~2為0.9979。H_2S、羰基硫的檢出限(S/N=3)分別為0.04 mg/m~3和0.07 mg/m~3;H_2S、羰基硫的定量限(S/N=10)分別為0.08 mg/m~3和0.12 mg/m3~;回收率均在96%~103%之間;對(duì)同一樣品重復(fù)測(cè)定8次,相對(duì)標(biāo)準(zhǔn)偏差均小于等于8.1%;與SCD氣相色譜法相比較,偏差符合氣相色譜法的定量要求。

測(cè)定煤基合成氣中硫化氫及羰基硫  測(cè)試譜圖:



Determination of hydrogen sulfide and carbonyl sulfide in coal-based synthesis gas
Determination of hydrogen sulfide and carbonyl sulfide in coal-based synthesis gas Details:

Name: Special column for sulfide determination

Material: PTFE tube

Model: HH-sulfide-III

Specifications: 3m*3mm

Operating temperature: 120°C
Haohan Chromatography (Shandong) Application Technology Development Co., Ltd. has established a gas chromatographic analysis method for the determination of H_2S and carbonyl sulfide content in coal-based syngas. The online dilution system was diluted to 5 concentrations, the relative retention time was qualitative, and the working curve was quantified by external standard method. The logarithm of the H_2S content and the logarithm of the peak area have a good linear relationship in the range of 0.07~0.30 mg/m3, and the correlation coefficient r2 is 0.9998; the logarithm of the carbonyl sulfide content and the logarithm of the peak area are in the range of 0.13~0.53 mg/m~3 The internal linear relationship was good, and the correlation coefficient r~2 was 0.9979. The detection limits (S/N=3) of H_2S and carbonyl sulfide were 0.04 mg/m~3 and 0.07 mg/m~3, respectively; the quantification limits (S/N=10) of H_2S and carbonyl sulfide were 0.08 mg/m~3, respectively. m~3 and 0.12 mg/m3~; the recoveries were all between 96% and 103%; the same sample was repeated 8 times, and the relative standard deviations were all less than or equal to 8.1%; compared with SCD gas chromatography, the deviation was in line with gas chromatography Quantitative requirements of the law.

Determination of hydrogen sulfide and carbonyl sulfide in coal-based synthesis gas Test spectrum:

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